聚氨酯防腐涂料综述

介绍了聚氨酯防腐涂料的种类、成分及其性能,并与现有的防腐涂料进行了比较。     

碳化硼涂覆的碳纤维的抗热氧化性研究

用自己合成的裂解能得到碳化硼的聚碳硼烷,对碳纤维进行涂层,并详细测试了涂层碳纤维的抗热氧化性能。     

湿热环境中油罐防腐设计

湿热环境中油罐的腐蚀主要体现为电化学腐蚀的特征，适宜的防腐措施对提高油罐的建设质量，减缓油罐的腐蚀速度，延长油罐的使用寿命，减小维护费用等具有积极的意义。从分析湿热环境中油罐腐蚀规律出发，介绍了油罐内外壁防腐涂层的选用原则，对3000m^3地面立式油罐的牺牲阳极电法保护进行了设计计算，提出了施工方法，对湿热环境中油罐防腐具有指导意义。     

Preparation and characterization of HMX/NH2-GO composite with enhanced thermal safety and desensitization

To improve the safety of HMX, HMX/NH₂-GO composite was prepared with aqueous ammonia functionalized graphene oxide (NH₂-GO). The composite was characterized by SEM, Zeta potential, XPS, Raman spectrum, XRD, HPLC, DSC and BAM sensitivity test. The results indicated that the functionalization with aqueous ammonia can enhance the interaction between GO and HMX, and more efficiently desensitize the explosive. The optimal impact sensitivity of the HMX/NH₂-GO composite can be not less than 40 J, which is also the most insensitivity compared to the previous reports prepared by coating desensitization with non-energetic desensitized material. Moreover, the potential reason for the different impact and friction sensitivity was also discussed, which may bring a novel perspective to achieve the desensitization of energetic material.     

Damage analysis of POZD coated square reinforced concrete slab under contact blast

High efficiency, environmental protection and sustainability have become the main theme of the development of the protection engineering, requiring that the components not only meet the basic functions, but also have chemical properties such as acid and alkali corrosion resistance and aging resistance. Polyisocyanate-oxazodone (POZD) polymer has the above characteristics, it also has the advantages of strong toughness, high strength and high elongation. The concrete slab sprayed with POZD material has excellent anti-blast performance. In order to explore the damage characteristics of POZD sprayed concrete slabs under the action of contact explosion thoroughly, the contact explosion test of POZD concrete slabs with different charges were carried out. On the basis of experimental verification, numerical simulation were used to study the influence of the thickness of the POZD on the blast resistance of the concrete slab. According to the test and numerical simulation results that as the thickness of the coating increases, the anti-blast performance of the concrete slab gradually increases, and the TNT equivalent required for critical failure is larger. Based on the above analysis, empirical expressions on normalized crater diameter, the normalized spall diameter and normalized spall diameter are obtained.     

一种新型CVD铁涂层吸波纤维

利用Fe(CO)5受热分解,以CVD方法在SiC纤维表面涂覆单质铁的涂层。研究表明,涂层的引入对SiC纤维力学性能基本没有损伤;纤维依靠涂层导电,其电阻率显著降低;改变工艺条件,可以在较大范围内调节涂层纤维的介电常数,同时也引入了磁损耗机制;采用较低的沉积温度和较高的载气流速,可以提高介电常数和磁导率,同时有好的频散效应。     

聚碳硅烷纤维无机化过程中弯曲的形成及对SiC纤维性能的影响

先驱体转化法制备连续SiC纤维无机化过程中有明显的失重和收缩,造成了纤维弯曲,从而影响了纤维的单丝强度和束丝拉伸性能。根据聚碳硅烷(PCS)纤维的无机化过程,探讨了SiC纤维弯曲的种类和形成原因,通过力学分析研究了弯曲对SiC纤维性能的影响;根据弯曲形成原因,提出利用加张热交联和加张烧成的方法解决纤维的弯曲问题,从而提高SiC纤维的性能。     

PIP工艺制备的C/SiC复合材料的氧化行为

PIP工艺制备的C/SiC复合材料中SiC基体富碳,因此增强体和基体均容易氧化。碳纤维和无涂层保护C/SiC复合材料试样在400~1300℃的氧化速率随温度升高而加快,低温为反应控制,高温为扩散控制。CVD-SiC涂层保护C/SiC复合材料和由CVD-SiC层、自愈合层、CVD-SiC层三层涂层保护C/SiC复合材料在400~1300℃的氧化先随温度升高而加快,然后减慢。三层涂层在800~1300℃有非常好的保护效果。扫描电镜照片显示自愈合层的玻璃态物质进入涂层裂纹中,填充裂纹且阻挡氧的通过,从而有良好的抗氧化保护效果。     

一种新型内孔热喷涂技术及涂层性能研究

介绍了一种新型的内孔热喷涂技术———离心雾化等离子喷涂技术,并阐述了该技术的工作原理和工作过程。通过试验制取了3Cr13涂层和铝涂层,使用扫描电镜、能谱仪和光学显微镜等仪器设备对2种涂层的表面和截面进行观察分析,结果表明,通过该技术制取的涂层具有和传统电弧喷涂层类似的组织结构,并具有氧化物含量低,喷涂粒子大等特点。     

Si(Al)C纤维先驱体聚铝碳硅烷的合成

采用低分子量固态聚碳硅烷和乙酰丙酮铝为原料,利用Si-H与乙酰丙酮铝之间的交联反应合成适于熔融纺丝的聚铝碳硅烷。研究了反应条件对产物数均分子量、软化点和组成结构的影响及交联反应程度与可纺性之间的关系。实验结果表明:随着反应温度的升高和反应时间的延长,反应程度提高,残余乙酰丙酮基减少,Si-O-Al交联支化结构增多,分子量和软化点增大,可纺性随之下降。当乙酰丙酮铝投料比为8%时,在370℃下反应4~6 h,可得到软化点为206~221℃,Al wt%=0.68%,具有良好可纺性的聚铝碳硅烷。